The Spanish women's SuperCopa semifinal will see an El Clasico battle as Barcelona were drawn against Real Madrid for the "Final Four" stage of the competition which runs from Jan. 17-23.
The other semifinal in the women's competition sees Atletico Madrid take on Levante. The venue for the competition has yet to be announced.
Leaders Barca are 22 points clear of Real Madrid at the top of the Liga Iberdrola after 15 games.
Barca eliminated third division side Linares Deportivo 2-1 on Wednesday to reach the round-of-16 of the competition.
Los Blancos have not won the Copa since the 2013-14 campaign during Carlo Ancelotti's first stint as Madrid coach.
Men's Copa del Rey draw
Atletico Baleares vs. Valencia
Girona vs. Rayo Vallecano
Sporting Gijon vs. Cadiz
Elche vs. Real Madrid
Real Sociedad vs. Atletico Madrid
Real Betis vs. Sevilla
Athletic Bilbao vs. Barcelona
Mallorca vs. Espanyol